Huntsman cycloaliphatic epoxy resin Our Araldite line of very low viscosity, di-functional cycloaliphatic epoxy resins are designed for epoxy formulators needing high-temperature resistance, good Understanding mechanisms of cycloaliphatic epoxy resin curing with anhydride is important for the preparation of new thermosetting polymer materials. <IMAGE> wherein x+y+z ranges from 4 to 6; and 4. The hardener methyl- Epoxy resins are often employed as electric insulating material because of their good mechanical properties and their high specific resistance. Acts as a curing agent. • Huntsman invented and commercialized the JEFFAMINE® PEA amine curing agents. EPONEX Resin 1510 is recommended as a building block resin for preparations of: 1) low viscosity/higher molecular weight epoxide resins ( e. In this work, the novel epoxy monomer was prepared through Friedel–Crafts condensation between 1-naphthol and DCPD, and then the epoxy monomer was reacted with paraformaldehyde and epichlorohydrin orderly to Cycloaliphatic epoxy resins are prepared by con- verting tetrahydrobenzaldehyde by Tischenko condensation to form an ole fi n which is epoxidised with a peracid following the reactions shown below Biomass-based cycloaliphatic epoxy resin (Epoxide-A) with two epoxycyclohexyls linked with an acetal group was synthesized by utilizing furfural as a major raw material through a facile two-step Cypoxy Insulators and Custom Components provide uncompromising performance in indoor and outdoor applications. The latter catalyzes the curing of the epoxy resin. presentsthe1H-NMRspectraofTMP,MECandDMTMP. Industries: Properties: Tech. Cycloaliphatic Epoxy Resins are anticipated to witness moderate growth, Some of the key players in the global low viscosity epoxy resin market include Huntsman Corporation, Dow Chemical Company, BASF SE, Evonik Industries AG, and Kukdo Chemical Co. The catalyzed and uncatalyzed reactions follow essentially different reaction mechanisms: anionic polymerization and polyaddition, respectively. High functional epoxy resins are preferred for high-performance: Coatings; Containment systems; Composites; Structural adhesives; Electrical laminating and As epoxy resins became more widely available following their development and commercialization in the late 1940s and mid-1950s, utilization of an ever-wider variety of amine compounds ensued. Due to its saturated ring structure, this resin is Epotec YDH-6000 is a cycloaliphatic epoxy resin supplied at low viscosity. The cycloaliphatic epoxy resins, CY 179 (bis-(epoxycyclohexyl)-methylcarboxylate) and CY 184 (cyclohexane-1,2-dicarboxylate) denoted further as CY-1 and CY-2, respectively were obtained from Huntsman. TRiiSO distributes a wide range of epoxy resins based on Bis Phenol A, Bis Phenol F, phenol novolac, and cycloaliphatic epoxies. Cycloaliphatic Amine cSt @ 25°C Flash Point, PMCC, °C Coatings Adhesives & Sealants Composites EP - Epoxy Curing Agent PM - Polymer & Resin Modifier IM - Intermediate S - Solvent / RD - Reactive Diluent AC Daicel EHPE3150 is a solid multifunctional cycloaliphatic epoxy resin that can be thermally cured or cured by cationic UV. The anhydride hardener from the same supplier of type Aradur 917 CH was used to cure the resin in the presence of an accelerator (1 Mechanical properties of epoxy resin composites modified by epoxy styrene‐butadiene latex. Abstract This paper describes methods of production and the fields of application of one of the cycloaliphatic amines—isophorone diamine. Range of curing agents offering different cure speeds for use with various epoxy resins. Coatings Aradur® 40 by Huntsman is a cycloaliphatic polyamine-based hardener. 8 Automatic pressure gelation, vacuum casting Toughened cycloaliphatic epoxy system for Despite the robustness of thermosetting coatings in various applications, prolonged exposure to acidic environments can cause gradual deterioration, leading to structural or functional damage. Huntsman’s resin systems for High-Pressure Resin Transfer Molding (HP-RTM) applications exhibit very low viscosity (<300 mPas), adjustable reactivity (pot life, curing), low shrinkage (<2%), The cycloaliphatic epoxy resin used in this study (bis-(epoxycyclohexyl)-methylcarboxylate) was obtained from Huntsman Advanced Materials (Netherlands) and is recognised under the trade name CY 179. 3 / 5 / 310 115 – 132 10,500 2. It is an epoxy resin without halogens, an aliphatic backbone, high oxirane content, low viscosity, weatherability, low dielectric constant and high cured Tg. In this study, cycloaliphatic epoxy resin 4,5-epoxycyclohexane-1,2-dicarboxylic acid diglycidyl ester (TDE-85) was used as a modifier to prepare a highly water-resistant soybean adhesive. 2005;438:144–54. Click for Quote or Sample. Product Typical Properties Description Application; Resin Type: Viscocity at 25 o C, Cp: WPE, g/eq. 65 cycloaliphatic epoxy resin blend was applied to the outer surfaces (Figure 3d) and the structure was cured on either a cylindrical mandrel (Figure 3e) or on a metallic plate when samples with Some of the applications of paint demand elevated properties in terms of performance and in such cases Paints Epoxy System is used in the back bone of paint manufacturing to give the product the desired properties. D. Its equivalent weight was 164~172 g/eq and the viscosity was 700~900 mPa·s at 25℃. Araldite® CY 5910 Aradur® HY 1235 Accelerator DY 062 Araldite® DW 9134 Silica 100 / 89 0. 05 1,800 - 2,800 164 - 176 0. Modified solid resin ARALDITE® GZ 7071 X 75 Solid resin in solution® ARALDITE® GZ 7071 X 75 / GY 783 Blend of solid resin in solvent with liquid resin ARALDITE® PY 4122-1 Flexible epoxy resin ERISYS® GE 35H Flexible reactive diluent PHENOXY PKHS-40 Increases hydrophobicity and adhesion ARADUR 3282-1 Surface tolerant PAA-adducts. Good abrasion resistance. and 150° C. It is simply not viable to create high performance products if the planet pays the price. Accelerated Hydrogenated Bisphenol A Epoxy Resin EPALLOY® 5001LC resin is an accelerated version of the cycloaliphatic diepoxide EPALLOY® 5000 resin. Huntsman Advanced Materials is a leading global material solutions provider. VOC free. XU 35610 benzoxazine resin has a glass transition temperature (Tg) of 320°F (160°C). 7 – 2. 15%. ALBIDUR® products are available in epoxy resins (aromatic or cycloaliphatic), in vinyl ester resins, in unsaturated polyester resins and in a polyol. [g/Eq] Colour (Gardner) Applications Acc. 1. The molecular structures of the cycloaliphatic epoxy–silicone resins were characterized by Fourier 12. These low viscosity resins can be cured by heat or by cationic UV cure. Min. Huntsman Corporation is a leading global thermoplastic polyamide resins for hot-melt adhesives. com Presented at a meeting of the Thermoset Resin Cycloaliphatic epoxy–silicone resins were successfully synthesized through a two-step reaction route: (і) hydrosilylation of 1,3,5,7-tetramethylcyclotetrasiloxane (TMCTS) and 1,2-epoxy-4-vinyl-cyclohexane (VCMX), (іі) blocking of unreacted Si H in (і) with n-butanol. Subsequent steps of the process comprise cooling the Epoxy Resin Supplier, Epoxy Curing Agent, Triethylene Teta 112-24-3 Huntsman Well Stocked for The Manufacture of Epoxy Resin Curing Agent, Modified Cycloaliphatic Amine Epoxy Hardener 1816 for Topcoating with Ipda FOB Price: US $3. and 250° C. It is designed for transformers, generators and motors. Epotec YDH-3000 is provides superior UV resistance and weatherability compared to standard Bis Phenol A epoxy resins as a result of its saturated cyclic rings. The The cure kinetics of two epoxy/amine resins, Araldite 2020 and AY103-HY956 widely used as adhesives in the restoration of works of art from glass or ceramic was investigated using FTIR spectroscopy. wherein x ranges from 2 to 6, or b. Typical service The two-component resin system Huntsman Araldite ® CY192-1, a cycloaliphatic epoxy resin (100 pbw), and its corresponding anhydride-type hardener, Huntsman Aradur ® HY 918-1 (100 pbw) , have been used by CEA Araldite® CY 184 by Huntsman is a low viscosity, hexahydrophthalic acid diglycidylester based epoxy resin. What is claimed is: 1. 26, Browse Huntsman's extensive product portfolio for details on amines, adhesives, coatings, and composites that apply to a broad range of industries. All feature long latency (long 06. Increasing demand of light weight high performance materials from the construction and automotive sectors coupled with the increasing demand for high performance materials in the wind power and aerospace industry is expected to drive the demand for epoxy resins for the forecast period. Epotec YDH-6000 is intended to be cured with anhydride curatives at elevated temperatures. The ring structure of cycloaliphatic amines gives higher temperature resistance and T g s to the cured resins than the ethylene diamine-based aliphatic amines while the toughness and elongation typically improve due to the higher Sn quadrupole coil impregnation system at CEA Saclay; two component cycloaliphatic epoxy resin (Huntsman Araldite® CY192-1), and its corresponding anhydride hardener (Huntsman Aradur® HY 918-1) in 100 : 100 pbw; 80 °C-24 h + 120 °C-34 h + 130 °C-12 h curing cycle. The epoxy formulation studied in this paper was obtained by mixing three components: a cycloaliphatic resin, a hardener and a catalyst. EPONEX cycloaliphatic epoxy resin is a high performance, Beyond its use as a sole epoxy resin, EPONEX Resin 1510 can be used as a building block to prepare a lower viscosity version of a higher molecular weight epoxy resin, by reaction with bisphenol A, CER Technology • CERs - Different from Standard Bisphenol-A Epoxy Resins like DER 331, EPON 828 • Standard Epoxy resins made from Epichlorohydrin and Bisphenol-A • CERs are made by oxidation of Cyclo Diglycidyl 1,2-cyclohexanedicarboxylate (Araldite CY 184, Huntsman Co. Offers good electrical insulation performance, high deflection temperature, excellent dielectric properties and high temperature- & UV resistance. 6) Ultra Low Viscosity Novolac resin modified with a Cycloaliphatic polyglycidyl ether (free of any The invention is an epoxy resin coating composition. Good adhesion, especially to damp concrete. The major commercial sources of the monomeric resins at present are the Huntsman Corporation Ltd and Hexion, Siloxanes are good flame retardants, which can be easily used for modification of epoxy resins. HOMOPOLYMERIZATION OF THE EPOXY RESIN The epoxy resin used in this study was 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexylcarbxylate (ERL 4221, eq. 7%. (canceled) 11. E. , USA) was used as a cycloaliphatic epoxy resin. Solvent based The resulting epoxy resins contain no hydrolysable chlorine content, and the epoxide groups are integral to the cycloaliphatic ring. Cycloaliphatic epoxy resin (CEP) with epoxide equivalent weight of 200–230 g/mol was supplied by Zhejiang Zidian New Material Co. It possesses compatibility at all concentrations with those resins and any epoxy resin curing agent. a polyether polyamine of the formula: NH2CH(CH3)CH2[OCH2CH(CH3)]xNH2 a. Once you have logged in or signed up, select the product size you are interested in and the datasheet will be visible for download if one is available. ARATHANE ® high performance polyurethane systems. The samples of the other epoxy resins prepared using 4140 likely contained mono-epoxy alcohol also because they were prepared in manner very similar to 4360. Czub [29] synthesized high-molecular-weight epoxy resins from modified natural oils and When used for epoxy resin curing, this amine can provide synergistic processing and cured resin performance advantages relative to simple mixtures of polyetheramines and cycloaliphatic amines. Parts made with Epotec YDH-6000 provide high temperature resistance up to 250C. 2. EPONEX™ Resins are unique low viscosity epoxy resins designed to have improved performance compared to conventional bisphenol-A (BPA) type resins, when formulated properly. ARALDITE ® Cycloaliphatic Epoxy Resins. Other matrices are available on request. 1-10. Order: GABEPRO™ GPE-221 by Huntsman is a cycloaliphatic, diepoxy functional compound. The concentration of mono-epoxy alcohol was almost 20% in 4360. 3. The curing kinetics and properties of the cycloaliphatic epoxy resin sources of the monomeric resins at present are the Huntsman Corporation Ltd and Hexion, while the curing agents can be sourced from a variety of chemical compa-nies. 0 ppm be- The cycloaliphatic epoxy resin used in this study (bis-(epoxycyclohexyl)-methylcarboxylate) was obtained from Huntsman Advanced Materials (Netherlands) and is recognised under the trade name CY 179. Ethyleneamines are widely used as hardeners in epoxy systems that are cured under ambient conditions, and are used to produce thermoplastic polyamide resins for hot-melt adhesives. It’s self A twostep procedure for the synthesis of siloxane-containing cycloaliphatic epoxy resins was performed by Tao et al. The composition according to claim 1, wherein the at least one cycloaliphatic epoxy resin (a1) without an ester group is a polyglycidylether of 1,2-cyclohexanediol, 1,3-cyclohexanediol, 1,4-cyclohexanediol (quinitol), for example, CY184 or CY179 which are low viscous cycloaliphatic epoxy resins available from Huntsman Corporation. All systems are qualified for CNG and hydrogen pressure vessels. The hardener was based, in reality, on a mixture of two chemical compounds, a hexahydrophthalic anhydride (70% w/w) and a methyl hexahydrophthalic Browse Huntsman's extensive product portfolio for details on amines, adhesives, coatings, and composites that apply to a broad range of industries. An appealing class of epoxy resins that can be used as an alternative to traditional bisphenol epoxides constitutes cycloaliphatic epoxy resins (CAE) (Fig. 225 – 245. The Araldite ® and Tactix epoxy resins produced by Huntsman are supplied in a range of viscosities, functionalities and epoxy equivalent weights for a wide range of industrial Huntsman’s cycloaliphatic epoxy resins are designed for use in indoor and outdoor applications such as medium- to high-voltage electrical insulation. 330 epoxy resin is a low viscosity bisphenol A epoxy resin commonly used in composite and casting applications. Key All investigated systems were prepared from 3,4-epoxycyclohexylmethyl-3′,4′-epoxycyclohexane carboxylate, a cycloaliphatic epoxy resin (Araldit CY179) supplied by Huntsman (Basel, Switzerland). HUNTSMAN 1564 Hot Epoxy System includes HUNTSMAN ARALDITE® LY 1564 epoxy resin and ARADUR® 2954 cycloaliphatic polyamine. The product offers improved UV resistance. 20%. 20–21 12. 140, Issue. Tough yet flexible, they are the building block of choice for numereous epoxy applications. Additional technical data on XTJ-504, XTJ-590, XTJ-506, HK-511 and BA-509 • Huntsman has provided over thirty years of service to the epoxy industry. This study Cycloaliphatic Epoxy Resins. A non-routine analytical technique (mass spectroscopy) was required to confirm the presence of mono-epoxy alcohol. 16) as they are superior in resistance toward the moisture and UV excellent electrical properties, low viscosity, impact resistance, good weather ability, and high thermal stability. This research report covers detailed industry analysis, facts & figures, growth Huntsman PT 810 Shikoku MA-DGIC: 1,1,2,2-Tetrakis(p-hydroxyphenyl)ethane: 180–220 195–230: Solid Solid: jER 1031 Epon 1031: Cycloaliphatic epoxy resins are often preferred for cationic curing due to their curing faster than the D. These products are consequently particularly suitable as a floor coating, the cycloaliphatic epoxy resins containing hydroxyl groups. It provides outstanding performance for UV resistance and anti-radiation Westlake Epoxy's cycloaliphatic epoxy resin EPONEX™ Resin 1510 is useful in applications where improved outdoor resistance, as compared to standard bisphenol A or bisphenol F d UV-resistant properties. Designed for reinforcement of semi-structural, integrated, fiber components such as lightweight composite sandwich panels used in automotive assembly, VITROX ® RTM 00410 resin system is As an alternative to the BPA-type epoxy resins, cycloaliphatic resins that are hydrogenated [28] BPA resins and the cycloaliphatic epoxy resins with the epoxy group in the cycloaliphatic ring [29], which show better weather resistance and lower tendency to undergo yellowing than the aromatic resins, constitute another class of epoxy resins that is of significant High-performance thermoset materials derived from epoxy resins have excellent properties, and are widely used. There are two main commercial types that offer low viscosity and excellent weathering and electrical performance. 3 Amidoamine and Polyamide The Araldite ® and Tactix epoxy resins produced by Huntsman are supplied in a range of viscosities, functionalities and epoxy equivalent weights for a wide range of industrial applications. Check how key trends and emerging drivers are shaping Epoxy Resin industry growth. Product. It has an epoxy equivalent concentration of 7. A method for limiting peak exotherm temperatures in an epoxy system comprising the step of: combining an epoxy resin, a polyetheramine, a cycloaliphatic amine and a diluent to form an epoxy system; wherein the diluent is selected from the group consisting of: ethylene carbonate, propylene carbonate, butylene carbonate, delta HUNTSMAN 1564 Hot Curing Epoxy System. ARADUR ® Curing agents. ARALDITE® PY 302-2 epoxy resin, is a commercially available epoxy from the Huntsman Corporation of The Woodlands, Texas High-T g epoxy networks were prepared from commercial cycloaliphatic epoxy resin ERL-4221 and cycloaliphatic anhydride MHHPA with and without tertiary amine DMBA as a catalyst. The search for new alternatives to commercial epoxy resin diglycidyl ether of bisphenol A (DGEBA), has prompted new investigations related to the development of novel epoxy monomers derived from renewable resources [1,2,3]. Araldite - Cycloaliphatic Epoxy Resin by Huntsman International LLC. Excellent arc tracking and thermal shock resistance. by Huntsman include epoxy resins, epoxy reactive diluents, curing agents and crosslinkers for epoxy resins, benzoxazines, cyanate esters, polyimides and bismaleimides. Nonflammable. ARL-135 LV Max 100 169 - 185 1,000 - 1,500 A modified epoxy resin recommended for fast impregnation of Huntsman offers a complete line of ethylene amines. 24. In this work, a cycloaliphatic epoxy resin hexahydrophthalic acid bis(3,4-epoxycyclohexylmethyl) ester (BE) was prepared and cured with anhydride. It is suitable for liquid epoxy resins. 10 2 Lowest viscosity Bis-F resin. 2000 – 3700. EPONEX cycloaliphatic epoxy resins are high performance products for use in adhesive, civil engineering, electrical, uses as curing agents for epoxy resins. Because of their high weathering resistance, cycloaliphatic epoxy resins are particularly suitable for outdoor use. Jay S. Aradur® 40 is recommended for use in flooring and solvent-free coatings 12. Epoxy: Benzoxazine resins are 50% stiffer than traditional epoxies with fl exural moduli in the 4,500 – 5,300 MPa range. Toughened cycloaliphatic epoxy system for medium-voltage applications. Yang et al. ARALDITE ® hydrophobic cycloaliphatic epoxy HUNTSMAN 1564 Hot Epoxy System includes HUNTSMAN ARALDITE® LY 1564 epoxy resin and ARADUR® 2954 cycloaliphatic polyamine. 960-1 Neat resin & hardeners (unmodified and without filler) evaluated as clear coatings 3 cycloaliphatic epoxy resins and 3 formulated cycloaliphatic amines hardeners Aromatic Bis-A DGE liquid epoxy resin was used as the epoxy control Solvent borne polyurethane based clear top coating used as a commercial technology benchmark Testing Protocol Cycloaliphatic epoxy resins are prepared by con- verting tetrahydrobenzaldehyde by Tischenko condensation to form an ole fi n which is epoxidised with a peracid following the reactions shown below Cycloaliphatic epoxy resin containing hydroxyl group (DMTMP) was prepared by the transesterification between methyl-3,4-epoxycyclohexane carboxylate (MEC) and trimethylolpropane JEFFAMINE® polyetheramines have a proven track record as epoxy curing agents. Application: ALBIDUR® products are used in all applications where improved toughness of the cured resin is desired without sacrificing other properties, especially heat-deflection temperature. . 6 / kg. 3-3. Several unique cycloaliphatic epoxy resins and amine-curing agent combi-nations have been developed, which provide low color, outstanding non-yel-lowing epoxy resin was used as a baseline control, referred to as Control. The Celloxide range of epoxy resins exhibit high heat distortion temperatures, excellent electrical insulation, and excellent transparency. However, in very rainy regions with highly polluted air there is the problem that a conductive layer of dirt/water can form on the Epotec YDH-3000 is also a hydrogenated Bis Phenol A epoxy resin and is a drop-in replacement for Epalloy 5000 (both have same CAS# 30583-72-3). The cycloaliphatic epoxy resin selected for this study was 3,4-epoxycyclohexane methyl-3′4′-epoxycyclohexyl-carboxylate (EEC). a triacrylate ester, reacted with a mixture of 3. Due to its saturated ring structure, this resin is expected to find utility in applications requiring ARALDITE® cycloaliphatic outdoor systems have been trusted by businesses worldwide for over 40 years for excellent weather resistance. The thermal and mechanical properties of the resulting polymer were evaluated with differential To improve the toughness and hydrophobic property of the cycloaliphatic epoxy resin (CEP), which is vital to application in high voltage insulation of outdoor transmission lines, 3 A variety of epoxy resins are available with functionalities in excess of 2 up to 8. a cycloaliphatic epoxy resin (hydrogenated bisphenol A resin), and 2. The liquid to semi-solid Araldite® epoxy resins or resin solutions (e. Burton, Principal Scientist Huntsman Corporation 8600 Gosling Road The Woodlands, Texas 77381 Office phone: 281-719-7487 bruce_burton@huntsman. The POSS reagent (glycidyl POSS, EP0409), was obtained from Hybrid Plastics (Hattiesburg, the epoxy resin composition of the invention makes possible coating products that have excellent processability, cure very rapidly, show practically no yellowing, and have a hard, glossy surface of high quality, even when used under cold, damp conditions such as 8° C. A Advances in epoxy adhesives. To develop new adhesive compositions, the effect of the chemical nature of the curing agent (linear and cycloaliphatic amines) on the curing kinetics, as well as the thermomechanical and strength characteristics, of epoxy Oligo-fluorosiloxane (DFOS) and epoxy-containing oligo-fluorosiloxane (DFEHOS) were synthesized by the hydrolytic condensation reaction to modify 3, 4-epoxycyclohexylmethyl-3, 4 All components of the epoxy resin system were supplied by Huntsman Advanced Materials (Netherlands). 10%. Our Araldite line of very low viscosity, di-functional cycloaliphatic epoxy resins are designed for epoxy formulators needing high-temperature resistance, good electrical insulation The preparation of ultra-thin CFRP laminates, which incorporate a cycloaliphatic epoxy resin reinforced with polyhedral oligomeric silsesquioxane (POSS) reagent nanofiller, using out-of-autoclave procedure is reported. ARALDITE ® Industrial Adhesives and Hardeners. cycloaliphatic epoxy resin; very hydrophobic character Cycloaliphatic epoxy resin (3 ′,4 ′-epoxycyclohexymethyl 3,4 epoxycyclohexane carboxilate [ CAE ]) is well known in the market by the name of GPE - 221 and is obtained by A novel tri-functional cycloaliphatic epoxy resin was synthesized starting from dicyclopentadiene. They have a variety of applications, including Aradur® 42 by Huntsman is a cycloaliphatic polyamine. Cycloaliphatic epoxy resins refer to a series of products obtained by oxidation with butadiene and acrolein as base materials and the mixture of hydrogen peroxide and peracetic acid as oxidant. 13410-58-7 30583-72-3. Cycloaliphatic Amine Cycloaliphatic Epoxy Resins (EPALLOY 5000 Series) Product Name Average Epoxy Functionality Viscosity at 25°C, cP EEW, g/eq HCC, max % Gardner Color, max Description / Use Bisphenol F Epoxy Resins EPALLOY 8220 2. and 80% relative humidity. Schlechte, in Advances in Structural Adhesive Bonding (Second Edition), 2023 1. 5%. The properties of the epoxy formulations containing the catalyst are described below. 1 ee/kg. It improves chemical and heat resistance. It is a hot curing epoxy system with a long working time suitable for RTM, infusion, wet lay-up, RoyOxy® RAR 935 by Huntsman is a cycloaliphatic epoxy resin (casting resin). Epoxy Resins are used in conjunction with epoxy curatives to produce high performance composites. EPALLOY® 5001LC contains no 1. 2020 EPALLOY® 5000 Page 1 of 2 Advanced Materials EPALLOY® 5000 Hydrogenated Bisphenol-A Epoxy Resin H-BADGE EPALLOY® 5000 resin is the di-epoxide of the cycloaliphatic alcohol hydrogenated bisphenol A. The physical proper-ties of the materials below are described in Table 1: • Control—Industrial standard Bisphenol A-type liquid epoxy resin • Epoxy 1, Epoxy 2, and Epoxy 3—Three Huntsman cycloaliphatic epoxy resins • Amine 1, Amine 2, and Amine 3—Three Araldite - Cycloaliphatic Epoxy Resin by Huntsman International LLC. [44] The epoxy resins produced showed excellent thermal stability with low The Epoxy Resin market is primary driven by the construction and industrialization. The composition according to claim 1, wherein the at This document discusses cycloaliphatic epoxy resins, which are characterized by saturated molecular structures. It is used as a reactive diluent for high viscosity epoxy resins in adhesives. 11. wt. Ethyleneamines are widely used as hardeners in epoxy systems that are cured under ambient Araldite® HCEP (hydrophobic cycloaliphatic epoxy) systems reduce current leakage due to their hydrophobic properties, and therefore further improve reliability and extend the life expectancy EPALLOY® 5000 resin is the di-epoxide of the cycloaliphatic alcohol hydrogenated bisphenol A. 2 Cycloaliphatic amines. R. 1 August 15, 2013 Acceleration of Amine-Cured Epoxy Resin Systems Bruce L. Epoxy novolac resins are broadly utilized as primary epoxy resins or as modifiers in multi-resin systems. Providing low viscosity , low volatility and the ability to cure under ambient conditions, our epoxy curing agents can be used as resin co-reactants or crosslinkers in coatings, Explore our line of Epoxy Novolac Resins–including Low Viscosity products– that offer the performance you need, Multi-functional (+/- 2. This paper describes a simple procedure to prepare a uniform and inert epoxy coating on fused-silica capillaries using a cycloaliphatic epoxide-based resin that can be cured with acid anhydride in Ambient curing systems - Huntsman. Wherever you look, a part of us is there From coatings to transportation and energy to construction, we’ve been enabling progress through Responsible Chemistry for over half a century Cycloaliphatic epoxy resins are known for their synthesis process that eliminates hydrolyzable chlorine, thus avoiding the hydrolysis of hydrolyzable chlorine to hydroxyl groups in conventional epoxies, which is very favorable for Chemical structure of materials used in this study, cycloaliphatic epoxy resin cured with anhydride in the presence of an accelerator (left) and octa-functional POSS (right). In contrast, fully saturated cycloaliphatic epoxy resins are better suited for outdoor exposures, All components of the epoxy resin system were supplied by Huntsman Advanced . JEFFAMINE ® RFD-270 amine can be used as an epoxy curing agent in coatings, adhesives or composites. A curable epoxy resin composition comprising (a) a cycloaliphatic diglycidyl compound as epoxy resin, and (b) an antioxidant (b1) alone or a combination of an antioxidant (b1) and an UV absorber (b2), characterized in that the antioxidant (b1) is a compound of the general formula (I) wherein R 1 =═—H, —OH, —O—C 1-18 alkyl, —C 1-18 alkyl, —C 5-12 the present invention relates generally to methods of producing epoxy resin systems and more particularly to the use of cycloaliphatic carbonates as reactive diluents in epoxy resin systems. Based on DSC and TGA studies, cycloaliphatic epoxy. Epoxy is a widely used thermosetting resin recognized for its exceptional performance in adhesives, coatings, and various other applications, attributed to its high tensile strength, stiffness, electrical performance, and chemical resistance. It is a hot curing epoxy system with a long Bruce L. Low VOC. g. The cycloaliphatic epoxy resin is the most pop-ular resin (Scheme 3B), which with an aliphatic back- For challenging applications, Huntsman benzoxazine resins are an ideal alternative to conventional epoxy, phenolic and BMI resin systems. The epoxy resin cured using a cationic photoinitiator under UV light, and the curing degree of the epoxy resin was beyond 90% within 40 s, as shown in Fig. The resin was a diglycidyl ester of hexahydrophthalic acid. 4. , USA) was used as a cycloaliphatic anhydride type curing agent. Easy to clean and apply. No benzyl acid salt. ARALDITE ® Bisphenol-F Epoxy Resins. Epoxy-clay nanocomposites are extensively employed across diverse industries. Araldite GY 250, GY 260 or GY 280) do not cure fully when processed solely with Aradur® 42 and consequently resulting films are brittle as well as tend to exude. The chemical structures of the resultant epoxy resin and its precursor were characterized with FTIR spectroscopy, EEW, 1 H NMR and Mass spectrographic analyses. CHDM. The high modulus material is stiffer than epoxy resins with a flexural and tensile moduli >5,000 MPa. The composition comprises: 1. ARL-135 Max 100 169 - 185 1,700 - 2,500 A modified epoxy resin recommended for FRP components and concrete structure strengthening. Coatings: Construction: Composites: All Others (1) EPONEX Resin 1510: Hydogenated BPA epoxy: 1800-2500: 210-220: Low viscosity Cycloaliphatic Glycidyl Ether of Hydrogenated Bisphenol-A Huntsman's range of ARALDITE® resin systems includes both epoxy/anhydride and epoxy/amine chemistries, with a range of glass transition temperatures. Cypoxy is a cycloaliphatic epoxy resin material that won't track, even in the harshest environments. Its unique portfolio including a broad range of epoxy resins and amine Solid isolated aliphatic polyamine adduct Cycloaliphatic polyamine Aliphatic polyamine Cycloaliphatic polyamide Cycloaliphatic polyamide With solid epoxy resin and solvent * Gel time Huntsman Advanced Materials Our Advanced Materials division is a leading Cycloaliphatic epoxy resins offer an improved environmental resistance in comparison with standard Bisphenol A or Bisphenol F denoted further as CY-1 and CY-2, respectively were obtained from Huntsman. improve compatibility between resins and curing agents. Applications. Suitable processes include: Casting; Filament winding; Automatic Pressure We manufacture our ethyleneamines via the ethylene dichloride/ammonia process. Hartwig A, Sebald M, Kleemeier M cycloaliphatic epoxy resin; very hydrophobic character. Hydrierter BPA-diglycidylether. These resins are two-part adhesives, consisting of a resin – A, based on a diglycidyl ether of bisphenol A, and a hardener – B which is either a cycloaliphatic amine XU 35610 Benzoxazine Resin is a bisphenol-A based thermoset system that produces dimensionally stable, virtually void-free composites. A method for limiting peak exotherm temperatures in an epoxy system comprising the steps of: forming an epoxy system consisting of an epoxy resin that is an aromatic glycidyl ether based upon a mixture of bisphenol A and bisphenol F, polyetheramine, a cycloaliphatic amine and 2% by weight up to 10% by weight of a diluent and The reaction of the polyfunctional cycloaliphatic epoxy resin with the multifunctional hydroxy compound in the presence of a heterogeneous surface-active catalyst may proceed at room temperature, preferably, at an elevated temperature comprised between 60° C. Download the Huntsman Renlam CY219 Epoxy Resin technical data sheet (TDS) and the Huntsman Renlam CY219 Epoxy Resin safety data sheet (SDS) from Silmid today. Room-temperature curing formulations based on EPALLOY® 5001LC resin will cure in significantly shorter times than those based on EPALLOY® 5000 resin. Journal of Applied Polymer Science, Vol. Curing Agents • Aradur ® Product range Characteristics Accelerators Viscosity 25°C [mPa s] Amine value [mg KOH/g] H+ active equiv. We also do contract / toll manufacturing. The anhydride hardener from the same supplier of type Aradur 917 CH was used to cure the resin in the presence of an accelerator (1 It can also be used as a reactive viscosity reducer and a modifier for improved color in BPA-based epoxy resins. Diglycidyl ether bisphenol A (DGEBA) is an extensively used monomer in the epoxy network, but despite its many advantages, its precursor, bisphenol-A, is considered toxic to human health. At Huntsman Advanced Materials, the future matters to us. A multiple component thermosetting epoxy resin composition comprising (A) at least one cycloaliphatic glycidyl-type epoxy resin without an ester group, (B) at least one curing agent selected from the group consisting of aliphatic amine, cycloaliphatic amine, and dicyandiamide, and (C) at least one silanized filler. , particularly between 80° C. specifications Safety data sheet Sample ipox ER 15. Epoxy resin has numerous applications, such as varnishes, tires Used in combination with liquid epoxy resins especially such as ARALDITE® DY-T resin, ARADUR® 20317 curing agent is suitable for the production of epoxy resin coatings. In recent years, interest in developing cycloaliphatic epoxy resins has increased, mainly due to concerns related to toxicological issues of The VITROX® RTM 00410 resin system. ARALDITE ® Diluents. With its exceptional low tendency to yellowing and chalking and its resistance to mechanical stresses, ARADUR® 20317 curing agent is a preferred component for the formulation of decorative floor The thermal and mechanical properties, morphologies, and light transmittance of the cured neat epoxy resin and EHDM-modified epoxy were investigated by differential scanning calorimetry, thermogravimetric analysis, tensile and impact testing, scanning electron microscopy, and ultraviolet-visible spectrophotometry. cycloaliphatic epoxy resin with an spirobislactone with lantha-num triflate as initiator: kinetics of the curing process. Burton Huntsman Corp. It gives a very high T g. [28] synthesized a low viscosity epoxy resin by reaction of polyethylene glycol and DGEBA epoxy resin. Selected curing agents included cycloaliphatic amine (Aradur 2954) and anhydride (Aradur 917 CH) used with an High Tg B-stage epoxy SMC system for parts close to the engine. Selected curing agents included cycloaliphatic amine (Aradur 2954) and anhydride (Aradur 917 CH) used with an accelerator (1 Autocatalytic Cycloaliphatic Epoxy Resin 83 Fig. 08. Our portfolio of adhesives, CTS offers specialized curing and toughening agents, resin adducts, and other high-performance epoxy resins used in a wide range The preparation of ultra-thin CFRP laminates, which incorporate a cycloaliphatic epoxy resin reinforced with polyhedral oligomeric silsesquioxane (POSS) reagent nanofiller, using out-of-autoclave Huntsman Advanced Material (Switzerland) GmbH; Gyula Cycloaliphatic epoxy resins have been used alongside silicones and ceramics for more than 30 years as insulation materials for outdoor A modified epoxy resin recommended for clear casting application. 137). CYCLOALIPHATIC EPOXY RESINS 14 GLYCIDYL AMINE BASED EPOXY RESINS 15 OTHER SPECIALTY EPOXY RESINS 15 FORMULATED RESINS AND WATERBORNE 16 Huntsman Advanced Materials EPN-1179 EPN-1180 (Araldite®) EPN-1183 GY-289 Momentive Specialty Chemicals EPON™ 154 EPON 162 been extended to the cure of cycloaliphatic epoxy resins for encapsulating high performance electronic components, including light emitting diodes. Low color. FT-IR spectra of (a) TMP, (b) MEC and (c) DMTMP. EPONEX™ Cycloaliphatic Epoxy Resin for Improved UV Resistance. The physical and chemical properties of Most investigations of epoxy resin coatings for CE have involved the most common form of epoxy resins, the reaction products of epichlorohydrin and bisphenol A [31], [33]. The hot/wet performance of the new resins is also better than that of epoxy materials. Thermo-chim Act. 4. We manufacture our ethyleneamines via the ethylene dichloride/ammonia process. In this paper, the curing of commercial epoxy monomer 4-epoxycyclohexylmethyl-3,4-epoxycyclohexane-carboxylate ERL-4221 with 4-methylhexahydrophthalic anhydride in the absence of catalyst was studied by two At Huntsman Advanced Materials, the future matters to us. Increase. No benzyl It is free from benzyl alcohol and is compatible with solid epoxy resin view more. 2 Cycloaliphatic Amine Based . Examples of these cycloaliphatic epoxies are provided below: 3,4 18 CYCLOALIPHATIC AMINES — MODIFIED Polyamines with at least one amino group attached directly to a saturated ring. ARALDITE ® Multifunctional Epoxy Resins. by reaction with bisphenol-A) and 2) low viscosity esters The goal of the present study is to synthesize a novel, heat-resistant epoxy resin containing both a naphthalene structure and a DCPD group. As an alternative to DGEBA, cycloaliphatic resins have The CY184 epoxy resin (EEW 144–172 g/eq) and Aradur 2954 cycloaliphatic amine curing agent were purchased from Huntsman Advanced Materials (Basel, Switzerland); the EP0409 glycidyl POSS was purchased from Hybrid Plastics (Hattiesburg, MS, USA), and the MTM441 was supplied as prepreg by Solvay Group (Wilton, UK). Our most proud of certificates include ISO9001, ISO14001, OHSAS18001 as well as full REACH certificate. Obviously, the disappearance of the peak at 4. 330 epoxy resin frequently crystallizes at room temperature; heating to 50-55°C restores the resin to ERISYS® GE-22 by Huntsman is a low viscosity, cycloaliphatic diepoxide, epoxidized cyclohexanedimethanol. CYCLOALIPHATIC EPOXY RESINS 14 GLYCIDYL AMINE BASED EPOXY RESINS 15 OTHER SPECIALTY EPOXY RESINS 15 FORMULATED RESINS AND WATERBORNE 16 Epoxy Resin Supplier, Curing Agent, We produce cycloaliphatic epoxy resins, photoinitiators and other specialty chemicals. , China. , Ltd. Because most amines are Stay up-to-date with Epoxy Resin research offered by HTF MI. EHPE3150 is suitable for use in electronic insulating materials, semiconductor and LED sealing, FRP composites, optoelectronic applications, and in Hydrophobic cycloaliphatic epoxy (HCEP) resins were used to apply hydrophobicity transfer to pollution to confirm the durability of hydrophobicity transfer effect (HTE). PREFORMING HP RESIN TRANSFER MOLDING 7 WET COMPRESSION MOLDING PULTRUSION SHEET MOLDING COMPOUND WET FILAMENT / TOWPREG WINDING AUTOCLAVE QUALITY IN ONE MINUTE Combining a novel process and fast-cure ARALDITE® epoxy solutions, highly structural parts with outstanding properties and quality can be A curable epoxy resin composition comprising (a) cycloaliphatic diglycidyl compound as epoxy resin, and (b) an antioxidant (b1) alone or a combination of an antioxidant (b1) and an UV absorber (b2), characterized in that the antioxidant is a compound of the general formula (I), wherein R1 = -H, -OH, -O-C1-C18-alkyl, -C1-C18-alkyl,-C5-C12-cycloalkyl being unsubstituted Huntsman Advanced Materials, the global market leader in multifunctional epoxy resins, has invested significantly during 2011, expanding its capacity and capability to produce multifunctional epoxy resins both in the United States and in Europe by doubling the capacity at its Monthey, Switzerland facility and enhancing its current capability to produce purified resins at its Aradur® 3243-1 Cycloaliphatic polyamine 220 - 360 280 - 360 95 60 ≤ 1 CE, IM Aradur® 3253-1 Cycloaliphatic polyamine 200 - 260 290 - 320 ~ 95 40 ≤ 1 CE 1 30% in xylene/butanol (1:1) I 2 With solid epoxy resin and solvent I * Gel time has been measured with Araldite® GY 250 Waterborne curatives Modified solid resin ARALDITE® GZ 7071 X 75 Solid resin in solution® ARALDITE® GZ 7071 X 75 / GY 783 Blend of solid resin in solvent with liquid resin ARALDITE® PY 4122-1 Flexible epoxy resin ERISYS® GE 35H Flexible reactive diluent PHENOXY PKHS-40 Increases hydrophobicity and adhesion ARADUR 3282-1 Surface tolerant PAA-adducts. Accelerators & Catalysts. 4-Methyl-1,2-cyclohexanedicarboxylic anhydride (Aradur HY 917, Huntsman Co. ueh wwnfblpo tmqrr trzhvw rsw jwd zzgew rswc zcinwd mofct